MSDS LDPE 2426K 安全技术说明书

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Lupolen 2426K

Ethene, homopolymer, PE

Polyethylene

9002-88-4

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the

Substance/Mixture

1.3 Details of the supplier of the safety data sheet

Company Telephone Registration number

Basell Sales & Marketing 31 (0) 10 275 55

NA

Company B.V. 00

Groot Handelsgebouw,

Stationsplein 45

3013 AK Rotterdam

Netherlands

E-mail address :

@

Responsible/issuing person

2. Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.

Classification according to EU Directives 67/548/EEC or 1999/45/EC, as amended

Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC.

2.2 Label elements

Labeling (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.

2.3 Other hazards

If small particles are generated during further processing, handling or by other means, may form

combustible dust concentrations in air.

This substance/mixture contains no components considered to be either persistent, bioaccumulative

and toxic (PBT) or very persistent and very bioaccumulative (vPvB).

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1.4 Emergency telephone

Emergency telephone

+32 3 575 1235

: Manufacture of plastic articles by injection moulding, extrusion

or other conversion process.

Trade name

Synonyms

Substance name

Substance No.

:

:

:

:

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

3. Composition/information on ingredients

3.2 Mixtures

Ingredients

Chemical Name CAS-No.

EC-No.

Classification

(67/548/EEC)

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

Polyethylene 9002-88-4 Not Classified

Classification

(REGULATION

(EC) No

1272/2008)

Not Classified

Weight %

> 99.5 %

Contains: Additives and stabilizers

4. First aid measures

4.1 Description of first-aid measures

General advice

If inhaled

: Take proper precautions to ensure your own health and safety

before attempting rescue and providing first aid.

: Remove person to fresh air. If signs/symptoms continue, get

medical attention.

In case of excessive inhalation of fumes that may be

generated during heating of this material, move the person to

fresh air.

Obtain medical attention.

Keep person warm, if necessary give Cardio-Pulmonary

Resuscitation (CPR)

: If molten material contacts the skin, immediately flush with

large amounts of water to cool the affected tissue and

polymer.

Do not attempt to peel polymer from skin as this will remove

the skin.

Obtain immediate emergency medical attention if burn is deep

or extensive.

: Flush eyes thoroughly with water for several minutes and seek

medical attention if discomfort persists.

: In case of eye contact with molten polymer:

Continuously flush eye(s) with cool running water for at least

15 minutes.

Beyond flushing, DO NOT attempt to remove the material

adherent to the eye(s).

Immediately seek medical attention.

: Adverse health effects due to ingestion are not anticipated.

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In case of skin contact

In case of eye contact

If swallowed

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

4.2 Most important symptoms and effects, both acute and delayed

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

: Inhalation of process fumes and vapors may cause soreness

in the nose and throat and coughing.

Hazards : Dust contact with the eyes can lead to mechanical irritation.

Molten polymer may cause thermal burns.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment

5. Fire-fighting measures

5.1 Extinguishing media

: SMALL FIRE:

Use dry chemical, CO2, or water spray.

: LARGE FIRES:

Use water spray hose nozzles from a safe location.

Unsuitable extinguishing : None known.

media

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire

fighting

: Keep away from heat and sources of ignition.

In case of fire hazardous decomposition products may be

produced such as:

Carbon monoxide, carbon dioxide and unburned

hydrocarbons (smoke).

: Wear approved positive pressure self-contained breathing

apparatus and firefighter protective clothing.

: Combustible particulate solid, will decompose under fire

conditions.

Calorific Value: 8000 - 11000 kcal/kg

Fight fire from safe distance with hose lines or monitor

nozzles.

Heat from fire may melt, decompose polymer, and generate

flammable vapors.

Move containers from fire area if it can be done without risk.

Evacuate immediately in the event of opening of storage

container pressure relief devices or discoloration of container.

Always stay away from tanks engulfed in fire.

Do not attempt to get on top of storage containers involved in

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Suitable extinguishing media

: Treatment of overexposure should be directed at the control of

symptoms and the clinical condition of the patient.

Symptoms

5.3 Advice for firefighters

Special protective equipment

for fire-fighters

Further information

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

fire.

Cool storage containers with large volumes of water even

after fire is out.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Equip responders with proper protection.

Creates dangerous slipping hazard on any hard smooth

surface.

Equip emergency responders with proper personal protective

equipment (PPE)

Avoid generating dust.

Avoid dispersal of dust in the air (i.e., clearing dust surfaces

with compressed air).

Potential combustible dust hazard.

Polymer particles create slipping hazard on hard smooth

surfaces.

6.2 Environmental precautions

: Do not flush into surface water or sanitary sewer system.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : On land, sweep/shovel into suitable disposal containers or

vacuum using equipment which avoids ignition risk.

On water, material is insoluble; collect and contain as any

solid.

All recovered material should be packaged, labeled,

transported and disposed of or reclaimed in conformance with

applicable laws and regulations and in conformance with good

engineering practices. Reclaim where possible.

Environmental precautions

7. Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Material is in a pellet form.

If converted to small particles during further processing,

handling, or by other means, may form combustible dust

concentrations in air.

Avoid dust accumulation in enclosed space.

Use dust collection systems designed in accordance with

ATEX 95.

Avoid generating dust; fine dust suspended in air and in the

presence of an ignition source is a potential dust explosion

hazard.

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

Fire-fighting class

Static discharge (spark), or other ignition sources, in high dust

environments may ignite the dust and result in a dust

explosion

Electrostatic charge may build during conveying or handling.

Equipment handling polymer should be conductive and

grounded (earthed) and bonded.

Metal containers involved in the transfer of this material

should be grounded and bonded.

All electrical equipment should conform to applicable electric

codes and regulatory requirements for areas handling

combustible dusts.

After handling, always wash hands thoroughly with soap and

water.

When bringing the material to processing temperatures vapors

may develop may condense in the exhaust ventilation. See

section 10.

: Refer to ATEX 95 and ATEX 137 and related Harmonized

European Standards: EN 1127-1 (Explosive atmospheres –

Explosion prevention and protection).

: Polymer will burn but does not easily ignite.

: Store in a dry location.

Use good housekeeping practices during storage, transferring

and handling. Process enclosures and adequate ventilation

should be used to avoid excessive dust accumulation.

Store away from excessive heat and away from strong

oxidizing agents.

Keep container closed to prevent contamination.

Take measures to prevent the build up of electrostatic charge.

: See Section 1.2.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage

areas and containers

7.3 Specific end use(s)

8. Exposure controls/personal protection

8.1 Control parameters

Ingredients with workplace control parameters

Occupational Exposure Limits

Ingredients CAS-No.

Type Limit Value

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Basis Additional

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

Materials that can

be formed when

handling this

product: Non-

specified (inert or

nuisance) dust

Materials that can

be formed when

handling this

product: Non-

specified (inert or

nuisance) dust

TWA 10 mg/m3

inhalable

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

Revision Date

US (ACGIH)

2005

Information

TWA 3 mg/m3

respirable

US (ACGIH)

2005

Consult local authorities for acceptable exposure limits.

8.2 Exposure controls

Engineering measures

In accordance with ATEX 137, follow the recommendations in EN 1127-1(Explosive atmospheres –

Explosion Prevention and protection).

Follow the recommendations in international standard NFPA 654 (as amended and adopted) for

equipment used to handle this product.

Engineering controls, i.e. enclosed systems, should be used whenever feasible to maintain

exposures below acceptable criteria. When such controls are not feasible, or sufficient to achieve full

conformance, other engineering controls such as local exhaust ventilation should be used.

Equipment and vessels handling combustible dust from this material should be designed to either

prevent dust explosions (inerting) or safely vent dust explosions per ATEX 95 and related

Harmonized European Standards.

Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing

equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is

no leakage from the equipment).

Personal protective equipment

Respiratory protection : Use process enclosures, local exhaust ventilation, or other

engineering controls to keep airborne levels below

recommended exposure limits.

When workers are facing concentrations above the exposure

limit they must use appropriate certified respirators.

Use appropriate respiratory protection where atmosphere

exceeds recommended limits.

Where workers could be exposed to dust concentratons

above the exposure limit they must use appropriate certified

respirators.

: Wear gloves that provide thermal protection where there is a

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Hand protection

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

potential for contact with heated material.

Eye and face protection : Dust service goggles should be worn to prevent mechanical

injury or other irritation to eyes due to airborne particles which

may result from handling this product.

Skin and body protection : Wear suitable protective clothing.

Hygiene measures : Selection of appropriate personal protective equipment should

be based on an evaluation of the performance characteristics

of the protective equipment relative to the task(s) to be

performed, conditions present, duration of use, and the

hazards and/or potential hazards that may be encountered

during use.

Use good personal hygiene practices.

Wash hands before eating, drinking, smoking, or using toilet

facilities.

Take off contaminated clothing and wash before reuse.

Environmental exposure controls

General advice

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

Color

Odor

Lower explosion limit

Upper explosion limit

Flammability (solid, gas)

Oxidizing properties

Autoignition temperature

pH

Melting point/range

Boiling point/boiling range

: Pellets.

: Translucent to white

: Slight.

: Note: The minimum explosive concentration (MEC) for

polymer dust varies according to particle size distribution.

: Note: Not applicable.

: Polymer will burn but does not easily ignite.

: Not considered an oxidizing agent.

: > 300 °C

: Note: Not applicable.

: 50 - 170 °C

: Note: Not applicable.

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: See section 6.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

Vapor pressure

Density

Water solubility

Partition coefficient: n-

octanol/water

Viscosity, dynamic

Relative vapor density

Evaporation rate

Explosive properties

9.2 Other information

10. Stability and reactivity

10.1 Reactivity

No known reactivity hazards.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous reactions

10.4 Conditions to avoid

Conditions to avoid

10.5 Incompatible materials

: Will not occur.

:

:

:

:

:

:

:

:

Note: Not applicable.

< 1 g/cm3

Note: Insoluble.

Note: No Data Available.

Note: Not applicable.

Note: Not applicable.

Note: Not applicable.

No Data Available.

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

: Avoid contact with strong oxidizers, excessive heat, sparks or

open flame.

: Material may be softened by some hydrocarbons.

10.6 Hazardous decomposition products

Hazardous decomposition

products

Thermal decomposition

: Not expected to decompose under normal conditions.

: Note: Carbon monoxide, olefinic and paraffinic compounds,

trace amounts of organic acids, ketones, aldehydes and

alcohols may be formed.

Materials to avoid

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Acute oral toxicity

Acute inhalation toxicity

Acute dermal toxicity

Skin corrosion/irritation

Serious eye damage/eye

irritation

Respiratory or skin

sensitization

Chronic toxicity

Carcinogenicity

Germ cell mutagenicity

Reproductive toxicity

Effects on fertility /

Effects on or via lactation

Effects on Development

: Not classified

: Not classified

Target Organ Systemic Toxicant - Single exposure

: Not classified

: Not an eye irritant.

Mechanical irritation is possible.

: Not a skin irritant.

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

:

Not classified

: Not classified

: Not classified

: Not classified

: Not classified

: The substance or mixture is not classified as specific target

organ toxicant, single exposure.

Target Organ Systemic Toxicant - Repeated exposure

: The substance or mixture is not classified as specific target

organ toxicant, repeated exposure.

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

Aspiration hazard

12. Ecological information

12.1 Toxicity

Ecotoxicology Assessment

Acute aquatic toxicity

Chronic aquatic toxicity

: Not classified

: Not classified

: Not applicable.

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

12.2 Persistence and degradability

Biodegradability

12.3 Bioaccumulative potential

Bioaccumulation

12.4 Mobility in soil

Additional advice

: This material is not volatile and insoluble in water.

Environmental fate and

pathways

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative

and toxic (PBT) or very persistent and very bioaccumulative (vPvB).

12.6 Other adverse effects

Additional ecological

information

: Ecotoxicity is expected to be minimal based on the low water

solubility of polymers.

No data available on this product. However, birds, fish and

other wildlife may eat pellets which may obstruct their

intestinal tracts.

: This material is not expected to bioaccumulate.

: Not expected to be biodegradable.

13. Disposal considerations

13.1 Waste treatment methods

Product : All recovered material should be packaged, labeled,

transported and disposed of or reclaimed in conformance with

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

applicable laws and regulations and in conformance with good

engineering practices. Reclaim where possible.

Recycle if possible.

14. Transport information

Not regulated for transport

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

REACh status

If the product has been purchased from any company of the LyondellBasell group of companies

registered in the European Union, we confirm that all substances in this preparation have been

pre-registered or, where required under REACh, registered, and that we have the intention to

proceed with their registration in accordance with the deadlines set forth in REACh. (Regulation

(EU) No. 1907/2006)

Other international regulations

Global Inventory Status

The ingredients of this product are compliant with the following chemical inventory requirements or

exemptions.

*Additional Explanatory Status Statements follow the table, as necessary.

Country/Region Inventory Status Description

Australia AICS Compliant

Canada DSL Compliant

China IECSC Compliant

Europe REACH See REACH Compliance Statement

Japan ENCS Compliant

Korea KECI Compliant

New Zealand NZIoC Compliant

Philippines PICCS Compliant

United States of America TSCA Compliant

Contact @ for additional global inventory information.

15.2 Chemical Safety Assessment

No information available.

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

16. Other information

Material safety datasheet sections which have been updated:

First Edition June 30 2014

Disclaimer

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

Multiple legal entities and registration numbers may be displayed in Section 1. The Recipient

shall refer to the shipping documents to identify the legal entity that supplied this product.

This document is generated for the purpose of distributing health, safety, and environmental

data.

Information is correct to the best of our knowledge at the date of the SDS publication.

It is not a specification sheet nor should any displayed data be construed as a specification.

Before using a product sold by a company of the LyondellBasell family of companies, users

should make their own independent determination that the product is suitable for the intended

use and can be used safely and legally. SELLER MAKES NO WARRANTY; EXPRESS OR

IMPLIED (INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A

PARTICULAR PURPOSE OR ANY WARRANTY) OTHER THAN AS SEPARATELY AGREED

TO BY THE PARTIES IN A CONTRACT.

This product(s) may not be used in:

(i) any U.S. FDA Class I, Health Canada Class I, and/or European Union Class I medical

devices, without prior notification to Seller for each specific product and application; or (ii) the

manufacture of any of the following, without prior written approval by Seller for each specific

product and application: U.S. FDA Class II Medical Devices; Health Canada Class II or Class III

Medical Devices; European Union Class II Medical Devices; film, overwrap and/or product

packaging that is considered a part or component of one of the aforementioned medical

devices; packaging in direct contact with a pharmaceutical active ingredient and/or dosage form

that is intended for inhalation, injection, intravenous, nasal, ophthalmic (eye), digestive, or

topical (skin) administration; tobacco related products and applications, electronic cigarettes and

similar devices, and pressure pipe or fittings that are considered a part or component of a

nuclear reactor. Additionally, the product(s) may not be used in: (i) U.S. FDA Class III Medical

Devices; Health Canada Class IV Medical Devices; European Class III Medical Devices; (ii)

applications involving permanent implantation into the body; (iii) life-sustaining medical

applications; and (iv) lead, asbestos or MTBE related applications. All references to U.S. FDA,

Health Canada, and European Union regulations include another country’s equivalent regulatory

classification.

The presentation of numerical data, such as that used for physical and chemical properties and

toxicological values, is expressed using a comma (,) to separate digits into groups of three and

a period (.) as the decimal marker. For example, 1,234.56 mg/kg = 1 234,56 mg/kg.

Adflex, Adstif, Adsyl, Akoafloor, Akoalit, Alastian, Alathon, Aquathene, Avant, Catalloy, Clyrell,

Dexflex, Flexathene, Hifax, Histif, Hostacom, Hostalen, Indure, Integrate, Koattro, Lucalen,

Luflexen, Lupolen, Metocene, Microthene, Moplen, Nexprene, Petrothene, Plexar, Pristene, Pro-

Fax, Purell, Sequel, Softell, Starflex, Ultrathene, and Valtec are trademarks owned or used by

the LyondellBasell family of companies.

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 and No. 453/2010

Lupolen 2426K

Version 1.0

Disclaimer

Revision Date 07/25/2014

Gen. Variant: SDS_GB

Print Date 09/19/2014

SDS No.: BE8226

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