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2024年12月27日发(作者:spring设计模式通俗理解)
装控131 杨哲 1304310125
CORROSION AND ANTICORROSION TECHNOLOGY
IN OFFSHORE PLATFORMS
(Shanghai Shipbuilding Technology Research Institute, CSSC 200032, China)
Abstract: This paper summarizes the corrosion environment and rules of the different
zones in offshore platforms, also briefly introduces the requirements and systems of the
anticorrosion coating .According to the long-term anticorrosion requirements in offshore
platforms, the paper introduces several long-term anticorrosion technology, including thermal
spraying, adding zinc protection and anticorrosion technology with platform legs wrapped
etc,which will provide some references to the research of the long-term anticorrosion technology
in offshore platforms.
Key words:offshore platform;anticorrosion; thermal spraying; adding zinc technology;
anticorrosion wrap
Offshore platform is a kind of large offshore engineering structure. The steel structure in the
long-term salt fog, moisture and water environment, the erosion of seawater and sea creatures,
and produce severe electrochemical corrosion. Corrosion seriously affects the mechanical
properties of the structure of the offshore platform, which affects the safety of the marine
platform. And because the offshore platform off the coast, not as a regular maintenance
like a ship docking, so builders and users of offshore platforms very seriously corrosion of
marine platform. How long-term preservation of offshore platform structure, as well as
research and development of offshore platform structure of the new materials, new
technologies and new processes are of long-term preservation is very important.
1. Corrosion Rules 1 offshore platform
1.1 Corrosion regional boundaries of the marine environment
Offshore platforms extremely harsh environment, sun exposure, salt spray, shock
waves, complex water system, environmental temperature and humidity changes and
marine life make offshore platforms erosion corrosion rate faster. Offshore platforms in
different marine environments, corrosion behavior and corrosion characteristics will be
relatively large differences. Therefore, to offshore platform structure in a marine
environment corrosion corroded areas were analyzed and defined, in order to put
forward effective protection measures. According to the marine environment,
corrosion characteristics and different average corrosion rate, offshore platform in the
marine environment in marine atmosphere can be divided into three major regions
splash zone and immersion zone. In order to better analyze the corrosion of steel
offshore platforms, many researchers turn splash zone into the splash zone and tidal
zone, immersion zone into seawater immersion zone and seabed soil area that is
divided into five areas of corrosion.
1.2
Marine steel corrosion
Ocean-atmosphere: Ocean sea-salt particles cause atmospheric zone accelerate
corrosion, dry surface and wet film alternates salt form of physical, chemical and
electrochemical action affecting metal corrosion.
Splash Zone: The most serious corrosion in the marine environment, the site is
above average tide splash zone. As often as the wet surface, surface oxygen supply is
sufficient, no sea biofouling. Long and short drying surface wetting the surface of the
alternation and spray erosion, mainly caused by physical and electrochemical corrosion
damage and maximum damage.
Tidal zone: steel corrosion tidal area is the lowest, even less than the corrosion rate
of seawater immersion and seabed soil. The average low tide level the following corrosion
nearby area emergence of a peak, it is because steel piles in the marine environment,
with tidal fluctuations, the total amount of oxygen in the steel surface above the waterline
humid than dip below the waterline at sea the steel surface to be much more fully, and to
each other to form a loop, thereby becoming an oxygen concentration difference between
the macro corrosion cell. Corrosion cell-enriched zone is the cathode, namely tidal area;
relatively anoxic zone anode, namely the regional average low tide level below the
waterline. The overall effect is that at every point throughout the tidal zone are subject to
varying degrees of cathodic protection. While the average low tide level less often as the
anode and the emergence of corrosion peak.
Seawater immersion zone: the corrosive seawater immersion zone, the shallow
water may corrode more quickly than the ocean air, the oxygen content of the deep-sea
areas is often much lower than the surface, the water temperature close to 0 oc, corrosion
lighter.
Seabed soil zone: the presence of sulphate reducing bacteria and bacterial sources
and characteristics of seafloor sediments mixed. Less influence by the sea, and the
temperature is low, a small degree of corrosion, but there is some corrosion at the junction
of ocean currents action.
2 offshore platform steel structure anti-corrosion coating technology
Long-term offshore platforms in harsh corrosive environments, maintenance difficulties
during use, so only use anti-corrosion technology provision of high-performance
heavy-duty coatings. Several offshore platform using heavy-duty coatings, each with the
following characteristics:
(1) zinc-rich primer: Requires a high proportion of zinc-containing paint, Kuang
requirements and substrate adhesion. One role is to take zinc-rich primer cathodic
protection, In addition, when the coating damage or when there is not continuous, zinc
Yao can play the role of sacrificial anode to protect the substrate. A zinc-rich primer Tong
inorganic zinc-rich primer, epoxy zinc-rich primer and the like.
(2) intermediate paint: intermediate paint requires comprehensive anti-corrosion ability,
among cattle is characterized by anti-rust paint or impervious material containing material
efficient, female l granular or scaly zinc powder, glass flake, stainless steel flake, satisfied
Mu class Chin shielded and powder-based coatings and cathodic protection type were
kind of new corrosion-type paints and so on.
(3) Finish: finish the role is to provide a protective layer of primer and intermediate coat,
slowed down and limited water vapor, oxygen, and chemical activity of ion penetration.
Also requires impact resistance, anti-aging and anti-insoluble and so on. Finish commonly
used chlorinated rubber, vinyl, polyurethane or acrylic resin coatings.
In addition, heavy-duty anti-corrosion coating to get a good effect, but also need to
pay attention to a number of factors, including the surface treatment of the substrate,
high-quality paint, reasonable coating system, outside construction conditions,
construction coating quality control. Currently heavy-duty coatings mainly used for
offshore platforms atmospheric zone.
l long-term preservation technology offshore platform
structure
For each area of corrosion offshore platforms, in addition to the current anti-corrosion
coating and cathodic protection or impressed current cathodic protection system support,
but also. on the offshore platform have long-term preservation of the use of other
technologies, including long-term platform for thermal spraying anti-corrosion technology,
Zinga protection technology, the platform leg tied corrosion package technology.
3.1 offshore platforms thermal spraying anti-corrosion technology
Thermal spraying technology in offshore platform steel member has a long history.
Thermal spraying of zinc, aluminum and its alloys coating on foreign offshore platform
steel member has successfully applied examples, examples show: thermal spray coating
of zinc-aluminum and its alloys corrosion has become a mature technology, after
appropriate heat sealed spray zinc-aluminum coating at room temperature and high
temperature on steel in the splash zone exhibited excellent corrosion resistance.
Aluminum thermal spray coatings in marine engineering is the biggest application
platform in 1984 to build the H otton tension leg platform. The platform design life of 50
years. 8 years after its use in the splash zone corrosion is found, and brown leakage
effects. Thickness measurement showed that the thickness of the coating does not reduce
platform installation, it illustrates the effect of anti-corrosion marine platform lame spraying
zinc aluminum metal coating layer is obvious, even if the surface of the organic coating off
will ensure expansion of the substrate against corrosion. At the same time after tests
showed that 2001} hot Tut m thick zinc-aluminum coating for steel in the splash zone
protection can ensure life for more than 30 years.
For high-strength steel parts used for offshore platforms, spraying aluminum and
aluminum alloy coating not only provides an aluminum shield, and once the coating is
damaged, it can appear as a sacrificial anode protection drain coating area. The coating
may be applied in a closed paint, aluminum and aluminum alloy coating to seal the pores,
thereby improving coating performance and extend the life of its total. Our thermal
spraying anti-corrosion technology started late, currently used in offshore platform
preservative it is still in the experimental stage, pending further development and
application.
3.2 Zinga offshore platform protection technology
Zinga protection is a quality and convenient method for steel corrosion protection, zinc
add protection to the substrate material has cathodic protection and shielding dual role.
Zinga protection technology has excellent corrosion resistance that Zinga zinc galvanized
coating dry film amounted to 9600, the product purity over 99.995% zinc. Zinga protection
also has a unique blend of heavy, new and existing coating Zinga Zinga coating can be
fully integrated, easy maintenance painted up.
Zinga protection compared with conventional organic coatings, cathodic protection
has a strong effect and may be used as a good bottom, its resistance to corrosion than
conventional zinc-rich primer 5-6 times, corrosion protection up to 25 years to 30 years.
The extent of corrosion of offshore platforms immersion zone serious than the
atmospheric region, but lighter than the splash zone. Full immersion zone generally use
cathodic protection or protective coatings and cathodic protection joint, but seldom alone
paint protection, since there is currently antirust, anti-fouling paint life is difficult to achieve
permanent protection of offshore platforms. Zinga protection technology in the dual role of
long-lasting protective coating and cathodic protection, corrosion protection with a long
service life which make up the general corrosion protection coatings in the life of
deficiencies.
Domestic and offshore platforms by the project proved plus zinc corrosion protection
properties of the coating technology is excellent. 2000 Zinga protection technology is
applied at the local service domestic and offshore drilling platforms, Shekou, Shenzhen
Pinghu oilfield offshore drilling platforms, repair of Zinga coating used has not found a
good rust and corrosion performance.
3.3 Offshore Platform Legs tied corrosion Package Technology
Currently, marine splash zone corrosion of the worst parts of the corrosion problem
has been unprecedented attention, and ongoing in-depth discussion among. Now
recognized as the most mature technology is corrosion Kit tied method. In the United
States, Britain, Japan and other developed countries, a growing number of offshore
platforms to splash zone corrosion leg using a preservative Kit tied technology.
Corrosion sets is a long-acting anti-corrosion technology, used in the splash zone of
marine environmental conditions can make corrosion life of more than 30 years. Corrosion
sets from high-strength multilayer fabric covered with special polyester outer layer, inner
cladding corrosion Thixotrope 3 parts. This three-layer structure closely aggregated
together to form a monolithic whole structure. This unique structure can be set by
increasing or decreasing the thickness of the body and alter the fabric structure to adjust
the physical properties of corrosion sets in order to adapt to different corrosion
requirements. Its multi-layer fabric itself elastic sleeve to make corrosion-designed
package tightly tied ocean tension leg platform, and watertight or airtight sealing
requirements, in order to achieve long-term preservation.
Offshore platform jacket leg corrosion can effectively solve the adverse effects of the
sea organism attachment. Anticorrosive coating the outer sleeve and the inner product of
antifouling component corrosion thixotropes and other unique design, can effectively
prevent the adhesion and growth of marine organisms, so that the corrosion sets
preservative life is greatly extended, and ultimately effective in achieving long-term
corrosion protection The purpose of. Its elasticity effect itself high strength fabric sleeve in
corrosion and piling surface tension of a tight collar, which will not only cover tightly pack
anticorrosive pile legs tied, and will not be due to temperature changes caused by steel
Pipe leg physical changes brought about by thermal expansion and contraction of any
effect. Currently, anti-corrosion sets of leg technique has been applied in more than one
marine projects around the world.
4 Conclusion
Offshore platform steel corrosion, according to the characteristics of the different
regions of maritime corrosion, corrosion rate choose the appropriate corrosion protection
measures. Anti-corrosion coatings emerging new varieties, should be fully aware of their
own performance matching paint and coating between strict coating process. Thermal
spray coatings and zinc plus protection technology is supporting each other coating and
cathodic protection, so as to achieve long-term preservation of the marine platform.
Offshore platforms leg in the splash zone area and the water level changes frequently
withstand collisions tapping and production operations and foreign matter waves is the
corrosion of the worst parts leg, requiring special corrosion protection. Package tied
corrosion technology has unique high strength jacket design, the marine platform leg may
get good corrosion protection effect of changes in the splash zone and district level. To
avoid the possible loss of corrosion, extend the life of offshore platforms, offshore
platforms anti-corrosion technology development is of great significance
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